Peppermint – This menthol-rich aromatic oil relieves migraine through its soothing smell. The relaxation it gives is long-lasting. However, peppermint may come too strong for some people who are sensitive to it, so it is advisable to mix it up with olive or coconut oil. It is also helpful to mix it with some vodka to gain instant relief against throbbing and pain. This oil is one of the oldest natural remedies to many other ailments.